Cosmetically? I think mascara is your all around best effect but lipstick is your quick pick-me-up.
Ohh??? Oblivion? Ahem, well ... I love this bow that Cain enchanted in Oblivion that will set on fire an army Captain and his whole squad of 10 or 12 men in one area-effect arrow. Not sure which bow he used though. Will ask when he wakes up.
I loved the dwemer crossbow in Morrowind. I'd enhance its stats and use orchish bolts with superhuge punch called KnockBack Bolts that would just make some Cliffracers explode in midair. ahahahaha!!! I also loved just about all the Daedric weapons - especially dai-katana, katana and bow/arrows.
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